@article{oai:tohoku-mpu.repo.nii.ac.jp:00000587, author = {加藤, 武 and Katoh, Takeru and 佐藤, 廣河 and Satoh, Hiroka and 平間, 美佳 and Hirama, Mika and 熱海, 秀 and Atsumi, Suguru and 成田, 紘一 and Narita, Koichi and 加藤, 正 and Katoh, Tadashi}, issue = {61}, journal = {東北薬科大学研究誌, Journal of Tohoku Pharmaceutical University}, month = {Dec}, note = {A novel synthesis of naphtoh[2,1-d]oxazol-5-ol, a model compound for the benzoxazole moiety of marine natural products nakijinols A and B, was achieved in five steps in 35% overall yield starting from commercially available 2-methoxy-1,4-naphthoquinone. The synthesis involved the following crucial steps: ⅰ reduction of an N-Boc-protected 2-amino-1,4-naphthoquione; ⅱ protection of the resulting 2-aminohydronaphthoquinone as its diformate form; ⅲ a simultaneous N-Boc-deprotection and cyclization of the resulting diformate to construct an oxazole ring.}, pages = {27--33}, title = {o-アミノフェノールのギ酸エステル誘導体を用いたベンゾオキサゾール環構築法の開発}, year = {2014}, yomi = {カトウ, タケル and サトウ, ヒロカ and ヒラマ, ミカ and アツミ, スグル and ナリタ, コウイチ and カトウ, タダシ} }